Page 120 - 2025水性涂料虚拟专辑
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第54卷第8期 涂料工业 Vol. 54 No. 8
2024年8月 卓 等:改性氧化石墨烯/水性环氧复合涂层的制备及性能研究 Aug. 2024
PAINT & COATINGS INDUSTRY
改性氧化 烯 水性环氧复合涂层的制备及性能研究
,尹 颖 ,赵 冰 ,王家 , ,张 文 *1
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(1. 江南大学化学与材料工程学院,江苏无 214122;2. 常州 程高分 材料有限公司,
江苏常州213000;3. 常州 新材料科技有限公司,江苏常州213000)
摘 要:为增进水性环氧树脂涂层的力学性能与耐腐蚀性,选用聚醚胺对氧化石墨烯(GO)边
缘羧基进行化学改性,并与水性环氧树脂复合制备了改性氧化石墨烯/水性环氧(AGO/EP)复合涂
层。探究了 AGO 的含量对复合涂层微结构、力学性能和耐腐蚀性的影响。结果表明:AGO 在水性
环氧中均匀分散且与水性环氧存在良好的界面作用,形成了一定有序层状结构,有效提升了水性环
氧树脂涂层的拉伸强度与断裂伸长率。水性环氧复合涂层(0. 5%AGO/EP)的低频阻抗模值达到
4. 47×10 ·cm ,AGO 的引入有效抑制了水汽和盐离子对钢板基材的腐蚀,复合涂层的耐盐雾腐蚀
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性能显著提高。
关键词:聚醚胺;氧化石墨烯;水性环氧;耐腐蚀性
中图分类号:TQ637. 81 文献标志码:A 文章编号:0253-4312(2024)08-0039-07
doi:10. 12020/j. issn. 0253-4312. 2024-049
Preparation and Properties of Modified Graphene
Oxide/Waterborne Epoxy Composites Coating
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HAN Zhuosa ,YIN Zhaoying ,ZHAO Yanbing ,WANG Jiaxuan ,GU Biao ,ZHANG Shengwen 1
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(1. School of Chemistry and Materials Engineering,iangnan University,Wuxi,iangsu 214122,China;. Changzhou
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Shuncheng Polymer Material Co Ltd Changzhou,iangsu 213000,China;3. Changzhou Enyao New Material
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Technology Co Ltd Changzhou,iangsu 213000,China)
Abstract:To improve the mechanical properties and corrosion resistance of water-based
epoxy coatings,polyether amine was used to chemically modify the carboxyl group at the edge
of graphene oxide(GO)to prepare modified graphene oxide(AGO),and modified graphene
oxide/waterborne epoxy(AGO/EP) composite coating was prepared by compounding with
waterborne epoxy resin. The effects of AGO content on the microstructure,mechanical
properties and corrosion resistance of composite coatings were investigated. The results showed
that AGO was uniformly dispersed in waterborne epoxy and had a good interface effect with
waterborne epoxy,orming a certain ordered layered structure,which enhanced the tensile
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strength and elongation at break of the coating. The low frequency impedance modulus of the
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water-based epoxy composite coating(0. 5%AGO/EP)reached 4. 47×10 ·cm . The addition
of AGO effectively inhibit the corrosion of water vapor and salt ions on the steel plate
*通信作者
本文规范引用格式:
韩 , 颖,赵彦冰,等. 改性氧化石墨烯/水性环氧复合涂层的制备及性能研究[J]. 涂料工业,2024,54(8):39-44,52.
HAN Z S,YIN Z Y,ZHAO Y B,et al. Preparation and properties of modified graphene oxide/waterborne epoxy composites coating[J]. Paint & Coatings
Industry,2024,54(8):39-44,52.
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