Page 46 - 涂层与防护2019-02

第 40 卷第 2 期 Vol.40 No.2
涂层与防护
2019 年 2 月 Feb.2019
COATING AND PROTECTION

POSS/ 丙烯酸酯复合材料的合成及在疏水中的应

用研究进展

张晓辰，范金福，李少香
（青岛科技大学，环境与安全工程学院，山东青岛 266042）

摘要：多面体低聚倍半硅氧烷(POSS)由于其纳米级有机-无机结构，且纳米级别的无机核被有机官能
团包围，使其成为构建纳米杂化材料和纳米复合材料的理想结构，引起了广泛的关注。 本文综述了 POSS
用于增强疏水性能的丙烯酸酯聚合物复合材料的最新进展，重点介绍了 POSS 作为疏水单元，采用物理或
共聚的方法与丙烯酸酯复合，合成不同结构的 POSS/丙烯酸酯复合材料，以满足所需的疏水要求。 POSS/丙
烯酸酯复合材料具有良好的疏水性能，同时具有优异的物理性能。
关键词：POSS；丙烯酸酯聚合物；复合材料；疏水性
中图分类号：TQ630 文献标识码：A 文章编号：1672-2418(2019)02-0030-09

Synthesis)of)POSS/Acrylate)Composite)and)Its
Application)in)Hydrophobicity

Zhang&Xiaochen,&Liu/Meng,&Fan/Jinfu,/Li/Shaoxiang
(Qingdao University of Science and Technology, College of Environment and Safety Engineering,
Qingdao, Shandong 266042, China)

Abstract:) Polyhedral oligomeric silsesquioxane (POSS) is silsesquioxane molecule with nano-
scaled organic /inorganic hybrid structure and its nano-sized inorganic nucleus is surrounded by
organic functional groups, which is regarded as an ideal structure for the construction of nano-hybrid

materials and nanocomposites, and has attracted much attention. In this article, a review is presented
of the recent development concerning the use of polyhedral oligomeric silsesquioxane (POSS) for
designing acrylate polymer composites endowed with enhanced hydrophobicity. Emphasis is placed
on the introduction of POSS as a hydrophobic unit. POSS/acrylate composites with different
structures were synthesized by physical or copolymerization to provide the required hydrophobicity.
POSS/acrylate composites showed a great potential to provide materials characterized by improved
hydrophobicity together with superior physical properties.
Keywords：POSS; acrylate polymer; composite; hydrophobicity

0 引言 状三维纳米结构，由硅和氧原子组成，可认为是尽可
能小的二氧化硅分子，通式为(RSiO 1.5) n 。 其中 n 是偶
多面体低聚倍半硅氧烷（POSS）是一种独特的笼 数，一般为 4、6、8、10 和 12，而关注最多的是六面体低

基金项目：山东省重点研发计划（2016CYJS09B01）

30 探索研究 RESEARCH AND DEVELOPMENT