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第54卷第5期                                       涂料工业                                     Vol. 54  No. 5
              2024年5月                    李永康等:高触变高抗流挂双组分水性环氧涂料的制备                                     May 2024
                                                   PAINT & COATINGS INDUSTRY


                         高 变高抗流挂双组分水性环氧涂料的制备




                                          李永  ,王   ,刘   ,  清                    *1,2
                                                                       3
                                                  1,2
                                                            1,2
                 (1. 江 科技  大学化学化工学院涂料与高分  ,南昌330013;2. 江 省水性涂料
                      工程研究中心,南昌330013;3. 江苏富  新材料有限公司,江苏南通226407)
                     摘 要:双组分水性环氧涂料具有触变性和抗流挂性不易调节的问题。采用聚氨酯缔合型增稠
                 剂和膨润土复配,并选用乳液型胺固化剂取代常用的水溶性胺固化剂的方式,制备了一款具有高触
                 变、高抗流挂和优异综合性能的双组分水性环氧涂料。研究了增稠剂和流变助剂的种类及用量、胺
                 固化剂的类型对双组分水性环氧涂料的触变性、抗流挂性及其他应用性能的影响规律,结果表明:
                 6870 乳液型胺固化剂与 299 增稠剂和 LT 膨润土之间存在相互促进作用,当 299 增稠剂用量为 0. 5%、
                 LT 膨润土用量为 0. 3% 时,搭配 6870 乳液型胺固化剂可制得触变指数为 4. 5、抗流挂极限膜厚为
                 475 μm、综合性能优异的双组分水性环氧涂料。
                     关键词:双组分水性环氧涂料;施工性;增稠剂;流变助剂;乳液型胺固化剂

                     中图分类号:TQ637. 81  文献标志码:A  文章编号:0253-4312(2024)05-0049-06
                     doi:10. 12020/j. issn. 0253-4312. 2023-283
                    Preparation of Two-component Waterborne Epoxy Coatings
                       with High Thixotropy and High Anti-sagging Resistance



                                            1,2
                                                             1,2
                                                                            3
                                Li Yongkang ,Wang Jiasheng ,Liu Shengpu ,Fu Changqing      1,2
                 (1. The  epartment of Coatings and Polymeric Materials,College of Chemistry and Chemical Engineering,iangxi
                                                                                                     J
                  Science & Technology Normal University,Nanchang   330013,China;. Jiangxi Engineering Laboratory of Waterborne
                                                                      2
                                                                                      J
                   Coating,Nanchang   330013,China;. Jiangsu Fu isen new material Co     Ltd     Nantong,iangsu   226407,China)
                                               3
                      Abstract:Two-component  waterborne  epoxy  coatings  have  the  problems  of  difficult
                 adjustment of thixotropy and anti-sagging resistance. In this paper,a two-component waterborne
                 epoxy coatings with high thixotropy,high anti-sagging and excellent comprehensive properties
                                                                                                    a
                 was prepared by the compounding of polyurethane association thickener and bentonite,nd the
                 selecting  emulsion-type  amine  curing  agent  to  replace  the  commonly  used  water-soluble
                 amine curing agent. The effects of the type and amount of thickeners and rheological additives,

                 and  the  type  of  amine  curing  agent  on  the  thixotropy,anti-sagging  and  other  application
                 properties  of  two-component  waterborne  epoxy  coatings  were  investigated. The  results  show
                 thatthere was a mutual promotion effect between the 6870 emulsion-type amine curing agent,

                 299 thickener and LT bentonite. When the dosage of 299 thickener was 0. 5% and the dosage
                                                                                          i
                 of LT bentonite was 0. 3%,with 6870 emulsion-type amine curing agent,t could produce a
                 thixotropic  index  of  4. 5,anti-sagging  limiting  film  thickness  of  475 μm,and  excellent

             *通信作者
             本文规范引用格式:
             李永康,王佳胜,刘胜 ,等. 高触变高抗流挂双组分水性环氧涂料的制备[J]. 涂料工业,2024,54(5):49-54.
             LI Y K,WANG  J  S,LIU S P,et al. Preparation of two-component waterborne epoxy coatings with high thixotropy and high anti-sagging resistance [J].
             Paint & Coatings Industry,2024,54(5):49-54.
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