Page 168 - 2025年7月防腐蚀专辑

第55卷第4期 涂料工业 Vol. 55 No. 4
2025 年4月 张玉 等：近红外光固化丙烯酸酯防腐涂料的制备及性能研究 Apr. 2025
PAINT & COATINGS INDUSTRY

红外光固化丙烯酸酯防腐涂料的制备及性能研究

张玉 ，解 旭，刘 仁，罗 静 *
（江南大学化学与材料工程学院，江苏无锡214122）

摘 要：为制备具有优异附着力和防腐性能的光固化金属防腐涂层，采用近红外光（NIR）诱导上
转换粒子辅助光聚合制备了光固化防腐涂层。探究了 NIR 固化体系的固化条件、涂层固化行为以及
不同官能度活性稀释剂所得涂层的附着力和防腐性能。结果表明：当光引发剂添加量为 2%、上转换
纳米粒子（UCPs）添加量为 4%、NIR 功率密度为 30 W/cm 时，聚合速率最快且双键转化率最高。相比
2
于 UV 固化体系，NIR 固化体系的表面/底面双键转化率均可达到 90%，还能够提高凝胶点双键转化
率，有利于降低固化收缩应力，从而提升涂层的附着力及耐腐蚀性。使用单官活性稀释剂的涂层表
现出最高的附着力，具有良好的防腐性能。NIR 固化为制备绿色环保高性能防腐涂层提供了一种新
策略，有望在金属防腐涂层领域取得更广泛的应用。
关键词：近红外光固化；活性稀释剂；金属防腐；防腐涂料
中图分类号：TQ637. 83 文献标志码：A 文章编号：0253-4312（2025）04-0060-09
doi：10. 12020/j. issn. 0253-4312. 2024-344
Preparation and Study on Properties of Near-infrared Light

Curable Anticorrosive Coatings

ZHANG Yuqing，XIE Xu，LIU Ren，LUO Jing
J
J
（School of Chemistry and Materials Engineering，iangnan University，Wuxi，iangsu 214122，China）
Abstract：The preparation of high-adhesion photocurable metal anticorrosive coatings
presented a significant challenge. This study explored the use of upconversion particle-
assisted near-infrared photopolymerization（NIR）to develop coatings with superior adhesion

t
and corrosion resistance. The curing conditions of the NIR system，he curing behavior of the
a
coatings，nd the adhesion and corrosion resistance of coatings formulated with multifunctional
reactive diluents were investigated. The results indicated that the polymerization rate was
fastest and the double bond conversion was highest when the concentrations of photoinitiator
and upconversion particles（UCPs）were 2% and 4% respectively，and the NIR power density

t
was 30 W/cm². Compared to UV curing systems，he NIR curing system achieved a double
bond conversion rate of 90% at both the top and bottom of the coating. Additionally，it
increased the double bond conversion at the gel point，which could reduce curing shrinkage
stress，hereby improving the adhesion and corrosion resistance of the coating. The coating with
t
monofunctional reactive diluent exhibited the highest adhesion，demonstrating excellent

*通信作者
本文规范引用格式：
张玉 ，解旭，刘仁，等. 红外光固化丙烯酸酯防腐涂料的制备及性能研究[J]. 涂料工业，2025，55（4）：60-67，74.
ZHANG Y Q，XIE X，LIU R，t al. Preparation and study on properties of near-infrared light curable anticorrosive coatings[J]. Paint & Coatings Industry，
e
2025，55（4）：60-67，74.
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