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第54卷第2期                                       涂料工业                                     Vol. 54  No. 2
              2024年2月                  孔明洁等:复配功能填料对无溶剂环氧涂层防腐性能的影响                                     Feb. 2024
                                                   PAINT & COATINGS INDUSTRY


                     复配 能填料对 溶剂环氧涂层防腐性能的影响



                                        明  ,    ,    ,                    , 小       *1
                                                        1
                                               1
                                                                  1
                                                                           2
                                (1. 青岛科技大学环境与安全工程学院,山东青岛266042;
                                 2. 青岛科技大学材料科学与工程学院,山东青岛266042)
                     摘 要:                             ,
                        SiO                 ,
                                 2
                  ,
                           EIS         ,
                    :              3 2,              1 1,
                      2 1,          SiO      3 1 ,               ,
                                                    2
                        ,  3. 5%NaCl      3 000 h  ,          6. 486×10 Ω·cm ,
                                                                                                   2
                                                                                            10

                     关键词:
                     中图分类号:TQ635. 2  文献标志码:A  文章编号:0253-4312(2024)02-0012-08
                     doi:10. 12020/j. issn. 0253-4312. 2023-241
                       Effect of Compounded Functional Fllers on Anticorrosive
                                Performance of Solvent-free Epoxy Coating


                                                                            2
                                             1
                                                        1
                                                                    1
                                Kong Mingjie ,Li Yufeng ,Zhao Jiayu ,Li Bin ,Yang Xiaogang  1
                  (1. College of Environment and Safety Engineering,Qingdao University of Science and Technology,Qingdao,
                    Shandong   266042,China;2. College of Material Science Engineering,Qingdao University of Science and
                                          Technology,Qingdao,Shandong   266042,China)

                      Abstract:This  paper  studied  the  influence  of  different  kinds  of  functional  fillers  on
                 solvent-free epoxy coating performance. Micaceous iron oxide and calcium exchange SiO  were
                                                                                                      2
                 selected  as  the  antirust  fillers  to  enhance  the  corrosion  resistance  of  the  coatings. Barium
                 sulphate  precipitated  with  ceramic  powder  were  used  to  improve  the  wear  resistance  of  the
                 coatings,and  solvent-free  epoxy  coatings  with  different  filler  compounds  were  prepared  by
                 orthogonal test method at the appropriate pigment/binder ratio. The effects of the mass ratio of
                 the fillers on the coating properties were analyzed and studied by basic physical property tests,
                                                       a
                 electrochemical impedance tests(EIS),nd salt spray resistance tests. The results showed that
                 the prepared coating possessed high impedance(R) along with excellent physical properties,
                                                                  c
                 at  the  mass  ratio  of  film-forming  substance  to  filler  of  3∶2,iller  to  antirust  filler  of  1∶1,
                                                                              f
                 ceramic powder to precipitated barium sulfate of 2∶1,and micaceous iron oxide to calcium-

             [基金项目] 国家自然科学基金资助项目(41106070); 山产业领军人才工程资助(tscy20221117)
             *通信作者:杨小刚(1977—),男,副教授,主要从事金属腐蚀与防护研究。
             本文规范引用格式:
             孔明洁,李 锋,赵家玉,等. 复配功能填料对无溶剂环氧涂层防腐性能的影响[J]. 涂料工业,2023,53(2):12-19.
             KONG  M  J,LI Y F,ZHAO  J  Y,et  al. Effect of compounded functional fllers on anticorrosive performance of solvent-free epoxy coating [J]. Paint  &
             Coatings Industry,2023,53(2):12-19.
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