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54   3                                                                                Vol. 54 No. 3
              2024  3                                                                                 Mar.  2024
                                                    A N    C A  NGS  ND S R


                   酚醛环氧乳液的制备及其漆膜耐热和燃烧性能研究



                                   张  磊 ,周如东 ,裴世博 ,任  强 ,汪称意 ,李  坚                       1
                                          1
                                                             1
                                                    2
                                                                       1
                                                                                1
                     (1. 常州大学材料科学与工程学院,材料科学与工程国家级实验教学示范中心,
                       江苏常州213164;2. 中海油常州涂料化工研究院有限公司,江苏常州213016)
                     摘 要:                   ,
                             ,           ,
                          ,    DSC  G       (MCC)
                           6                1 1        6
                    ,      900 nm,
                 98. 78  ,800        17. 7 ,           A
                                    A          ,                                                                     探
                     关键词:
                                                                                                                     索
                     中图 类号   630. 4  文献标志码:A  文章编号:0253-4312(2024)03-0015-07
                     doi 10. 12020  . i  n. 0253-4312. 2023-245
                                                                                                                     开
                     Preparation o  Phenolic Epo y Emulsion and Study on Heat                                        发
                            Resistance and Com ustion Resistance o  Coating


                                                              1
                                                   2
                                                                                        1
                                                                          1
                                     1
                            han   ei , hou Rudon  , ei Shi o ,Ren  ian  , an  Chenyi , i  ian    1
                  (1. School of Materials Science and Engineering,Changzhou University,National Experimental Demonstration
                    Center for Materials Science and Engineering,Changzhou,iangsu   213164,China 2. CNOOC Changzhou
                                                                  J
                                                                              J
                         Paint & Coatings Industry Research Institute Co     Ltd     Changzhou,iangsu   213016,China)

                        stract n order to de elop phenolic epo y  a ed  ilm  ormin  material with hi h heat
                 re i tance,t could meet the re uirement  o  heat re i tance o   ire retardant coatin  .  henolic
                            i
                 epo y emul ion wa  prepared  y pha e in er ion techni ue,nd the e  ect  o  emul i ier type,
                                                                           a
                 emul i ier  do a e,and  co- ol ent  do a e  on  the  propertie   o   emul ion  were  di cu  ed   y
                 ortho onal e perimental ran e analy i  method.  he heat re i tance and  ire re i tance o  the
                 cured  ilm were  tudied  y DSC, G and MCC.  he re ult   howed that the phenolic epo y
                 emul ion  wa   prepared  with  the  emul i ier  o   6   hydro yl   roup  and  epo y   roup  material
                                                  t
                                                                                        t
                 ratio  o   1 1  and  6   co ol ent,he  a era e  particle   i e  wa   900 nm,he  di tri ution  wa
                 uni orm  and  the   ta ility  wa    ood.  he   la    tran ition  temperature  o   phenolic  epo y
                 emul ion wa  98. 78  ,and the car on re idue rate wa  17. 7  at 800  , oth o  them were
                  i ni icantly  hi her  than  tho e  prepared   y  ordinary   i phenol  A  epo y  emul ion.  he  heat
                 relea e rate o  phenolic epo y  ilm durin  com u tion wa  lower than that o  ordinary  i phenol


              通信作者: 如  1982— , , 级工程 ,主要研究方向为 种  涂料新 料。
                      任 (1977—), , 授,主要研究方向为  基涂料、防 涂料、防 涂料。
             本文  引 格式:
               , 如 ,   ,等.       的制备及其    和  性 研究   . 涂料工业,2024,54(3):15-20,25.
               ANG   ,      R  D, E  S B,et  al.  reparation o  phenolic epo y emul ion and  tudy on heat re i tance and com u tion re i tance o  coatin     .
              aint   Coatin    ndu try,2024,54(3):15-20,25.

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